As well as putting the hours in learning Adobe Lightroom V4 I am now starting to learn whats new in CS6. The above shot of Dani was done on a simple white background with some gel filters over the flash heads lighting the background.
All I have done in CS6 is clean up the background somewhat. With the improvements in LR4 Photoshop is becoming less and less of a requirement but there are still aspects of retouching and cleaning up of an image that is faster and easier with Photoshop.